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Synthesis and Electrochemical, Electro-optical Properties and Electrochromic Behavior ……

Two new kinds of dithienylpyrroles derivatives (1-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)-anthraquinone (SNS-1AQ) and 2-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)-anthraquinone (SNS-2AQ)) have been prepared. The corresponding polymer films were successfully synthesized via electropolymerization. The structures of these…

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Two new kinds of dithienylpyrroles derivatives (1-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)-anthraquinone (SNS-1AQ) and 2-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)-anthraquinone (SNS-2AQ)) have been prepared. The corresponding polymer films were successfully synthesized via electropolymerization. The structures of these compounds were characterized and ensured by 1H NMR, 13C NMR, MS and FT-IR. The corresponding polymer films were successfully synthesized via electropolymerization in three-electrode system. Their spectroelectrochemical properties, electrochromic behavior, thermal stability, surface morphology, and fluorescence were investigated by cyclic voltammetry, UV-VIS absorption, thermogravimetric analysis, scanning electron microscopy and fluorescence emission spectra. The results show that these polymer films have excellent spectroelectrochemical and electrochromic properties. http://www.sjfcd.org/paperInfo.aspx?ID=961

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Synthesis and Electrochemical, Electro-optical Properties and Electrochromic Behavior of Properties of Two New Dithienylpyrroles Derivatives and Their Polymer Filmsaspx26 KB
Two new kinds of dithienylpyrroles derivatives (1-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)-anthraquinone (SNS-1AQ) and 2-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)-anthraquinone (SNS-2AQ)) have been prepared. The corresponding polymer films were successfully synthesized via electropolymerization. The structures of these compounds were characterized and ensured by 1H NMR, 13C NMR, MS and FT-IR. The corresponding polymer films were successfully synthesized via electropolymerization in three-electrode system. Their spectroelectrochemical properties, electrochromic behavior, thermal stability, surface morphology, and fluorescence were investigated by cyclic voltammetry, UV-VIS absorption, thermogravimetric analysis, scanning electron microscopy and fluorescence emission spectra. The results show that these polymer films have excellent spectroelectrochemical and electrochromic properties.
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